不同生物质焦-高铁赤泥复合球团热还原对比研究
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作者单位:

1.东北大学 冶金学院,辽宁 沈阳 110819 ;2.多金属共生矿生态化利用教育部重点实验室,辽宁 沈阳 110819

作者简介:

苏思羽(2000—),女,辽宁抚顺人,硕士研究生,主要从事固废回收再利用研究。

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中图分类号:

TF821;X758

基金项目:

辽宁省自然科学基金联合基金面上项目(No. 2023-MSBA-114);第九届青托工程项目(No. 2023QNRC001);鞍钢绿色资源技术有限责任公司技术开发项目(No. AGLYKJZLZX-2024-01)


Comparative study on thermal reduction of different biomass coke high iron red mud composite pellets
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Affiliation:

1.School of Metallurgy, Northeastern University, Shenyang 110819 , China ;2.Key Laboratory of Ecological Metallurgy of Multi-metal Intergrown Ores of Ministry of Education, Shenyang 110819 , China

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    摘要:

    基于生物炭相较于传统煤炭能源具有含氢量多、含碳量少、含氧量多、含硫量低等特点,本文研究了三种生物质焦-高铁赤泥复合球团的热还原机理,对比了三种生物质焦对球团金属化率、物相结构、微观形貌以及孔径的影响,得出以下结论。麦麸焦在复合球团金属化率、物相结构方面比其他两种生物质焦复合球团均有一定的优势,在 1 100℃下热还原 2 h,金属化率达到 86.5%,比冶金焦提高 5.2%, 远高于相同条件下松木焦复合球团与玉米焦复合球团;麦麸焦-高铁赤泥复合球团主要物相组成为金属铁(44.3%)、碳(10.6%)、钙铝黄长石(Ca2Al2SiO7 )以及霞石(NaAlSiO4 ),适用于涡流熔融还原炼铁工艺;麦麸焦-高铁赤泥复合球团气孔结构更为均匀,孔径约为2~4 nm,比表面积较大,整体结构较好,表面金属化程度更高,残余杂质较少。该研究结果对实现生物质资源高效利用具有重要的参考价值。

    Abstract:

    Based on the characteristics of biochar containing more hydrogen, less carbon, more oxygen, and lower sulfur compared with traditional coal energy, this study investigates the thermal reduction mechanism of three types of biomass char-high iron red mud composite pellets, and compares the effects of three biomass chars on metallization rate, phase structure, micromorphology, and pore size. The following conclusions were drawn. Wheat bran char exhibits superior performance in enhancing the metallization rate and optimizing the phase structure of the composite pellets compared to the other two biomass chars. After thermal reduction at 1 100℃ for 2 h, the metallization rate reaches 86. 5%, which is 5. 2% higher than that of metallurgical coke and much higher than those of pine wood char composite pellets and corn char composite pellets under the same conditions. The main phase compositions of wheat bran char-high iron red mud composite pellets are metallic iron (44. 3%), carbon (10. 6%), gehlenite (Ca ?Al ? SiO?), and nepheline (NaAlSiO?), making them suitable for the vortex melting reduction ironmaking process. The wheat bran char-high iron red mud composite pellets possess a more uniform pore structure with a pore size of approximately 2-4 nm, a larger specific surface area, a better overall structure, a higher degree of surface metallization, and fewer residual impurities. The research results provide important reference for the efficient utilization of biomass resources.

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苏思羽,刘燕,刘珈维,等 . 不同生物质焦-高铁赤泥复合球团热还原对比研究[J]. 中国有色冶金,2026,55(1): 155-164

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  • 收稿日期:2025-06-25
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  • 在线发布日期: 2026-03-27
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