镁渣在无机材料制备中的资源化利用研究现状及进展
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1.东北大学 冶金学院,辽宁 沈阳 110819 ;2.东北大学 低碳钢铁前沿技术教育部工程研究中心,辽宁 沈阳 110819 ;3.东北大学 辽宁省低碳钢铁前沿技术工程研究中心,辽宁 沈阳 110819

作者简介:

盖学鑫(1999—),男,辽宁朝阳人,硕士研究生,研究方向为镁渣的利用、多孔无机聚合物以及陶瓷材料的制备。

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中图分类号:

TF822;X758

基金项目:

中央高校基本科研业务费项目(N25YJS003)


Research status and progress of resource utilization of magnesium slag in the preparation of inorganic materials
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1.School of Metallurgy, Northeastern University, Shenyang 110819 , China ;2.Engineering Research Center of Frontier Technologies for Low-carbon Steelmaking (Ministry of Education), NortheasternUniversity, Shenyang 110819 , China ;3.Liaoning Low-carbon Steelmaking Technology Engineering Research Center, Northeastern University, Shenyang 110819 , China

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    摘要:

    我国每年镁渣排放量约 800万 t,受处理成本和技术等因素限制,多数镁渣被无序堆存或填埋,诸多学者对镁渣的资源化利用进行了探索。本文系统综述镁渣的理化特性、环境危害以及近年来资源化利用途径,重点探讨其在胶凝材料、水泥熟料以及固碳材料等领域的应用瓶颈与改进策略,为镁渣的综合利用提供理论支撑与技术参考。镁渣的主要成分为 CaO 和 SiO2,矿物组成以 β-C2S 和 γ-C2S 为主,已在胶凝材料、陶瓷、固碳材料等领域得到尝试性利用。镁渣在胶凝材料和水泥熟料掺合剂方面的研究较多,用于胶凝材料时需配合其他工业固废协同使用,以提升活性、改善力学性能,也可通过物理或化学激发释放其潜在的胶凝材料活性;作为水泥熟料掺合剂时,要考虑其掺量的影响。镁渣在高附加值创新领域表现出良好的应用潜力:镁渣基固碳材料具备成本低、强度高、较为稳定等优势,可应用于道路基层和充填矿山等领域;镁渣蓄热陶瓷凭借高蓄热密度和优异的热稳定性,适用于太阳能热发电系统的储热介质;镁渣吸附剂可实现污染物的去除;镁渣可以代替传统贵金属用作催化剂,降低生产成本。目前镁渣的实际利用率仍然很低,在胶凝材料领域的主要问题是活性低、体积不稳定、激发技术成本高,仍需进行持续探索;未来,镁渣的综合利用可以在高附加值领域及矿山充填领域进行研究,拓宽其可利用范围。

    Abstract:

    China generates approximately 8 million tons of magnesium slag annually. Constrained by treatment costs and technological limitations, most magnesium slag is currently stored haphazardly or landfilled. Numerous scholars have explored the recent resource utilization of magnesium slag. In this paper, the physical and chemical properties, environmental hazards and resource utilization of magnesium slag are systematically reviewed. The key points and improvement strategies of its application in cementitious materials, cement clinker and carbon sequestration materials are discussed, which provides theoretical support and technical reference for the comprehensive utilization of magnesium slag. Primarily composed of CaO and SiO?, with a mineral composition dominated by β -C ? S and γ -C ? S, magnesium slag has been explored of applications in cementitious materials, ceramics, and carbon sequestration materials. Extensive research exists on magnesium slag as a cementitious material and cement clinker admixture. When used in cementitious materials, it requires synergistic application with other industrial solid wastes to enhance reactivity and improve mechanical properties. Its latent cementitious activity can also be released through physical or chemical activation. As a cement clinker admixture, its dosage impact must be carefully considered. Magnesium slag exhibits promising application potential in high-value-added innovation fields: magnesium slag-based carbon sequestration materials offer advantages such as low cost, high strength, and relative stability, with future applications in road subgrades and mine backfilling; magnesium slag thermal storage ceramics, with their high specific heat capacity and excellent thermal stability, are suitable as heat storage media for solar thermal power generation systems; magnesium slag adsorbents can achieve contaminant removal; magnesium slag can replace traditional precious metals as catalysts, reducing production costs. At present, the actual utilization rate of magnesium slag is still very low. The main problems in the field of cementitious materials are low activity, unstable volume and high cost of excitation technology, which still need to be explored continuously. In the future, the comprehensive utilization of magnesium slag can be studied in high value-added fields and mine filling fields to broaden its available range.

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盖学鑫,傅大学,闫姝,等. 镁渣在无机材料制备中的资源化利用研究现状及进展[J]. 中国有色冶金,2026,55(1): 24-35.

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  • 收稿日期:2025-07-20
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  • 在线发布日期: 2026-03-27
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