废旧高温合金夹杂物的产生及净化工艺研究进展
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作者单位:

1.昆明理工大学 冶金与能源工程学院, 云南 昆明 650031 ;2.中国科学院过程工程研究所介科学与工程全国重点实验室, 北京 100190 ;3.中国科学院过程工程研究所战略金属资源绿色循环利用国家工程研究中心, 北京 100190

作者简介:

展开(1999—),山东枣庄人,硕士研究生,主要从事废旧高温合金回收再利用的研究。

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中图分类号:

TF804;TF125.2

基金项目:

国家重点研发计划项目资助(2022YFC3902001);HY行动项目(JK2022HYB0710A)


Research progress on production and purificationtechnology of waste superalloy inclusions
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Affiliation:

1.Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093 , China ;2.State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering,Chinese Academy of Science, Beijing 100190 ,China ;3.National Engineering Research Center of Green Recycling for Strategic Metal Resources, Institute of Process Engineering,Chinese Academy of Science, Beijing 100190 , China

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    摘要:

    高温合金在航天、航空、能源等高端制造业得到了广泛应用,每年产生大量的废旧料,废旧高温合金的净化与再生技术对推动我国高技术产业的健康发展具有重要意义。高温合金中的夹杂物主要来源于熔炼过程中的化学反应、服役环境中的元素污染以及加工存储过程中的外来杂质。这些夹杂物根据成分和形态可分为氧化物、硫化物、氮化物等多种类型,这些夹杂物的存在会显著降低材料的机械性能、耐腐蚀性和疲劳寿命,甚至导致关键部件失效。6种主流净化工艺包括机械滚磨、电渣重熔、真空感应熔炼、泡沫陶瓷过滤、电子束熔炼和底吹气泡浮选技术。其中,机械滚磨适用于表层夹杂物的去除,成本较低但处理深度有限;电渣重熔能有效去除大尺寸夹杂物,但存在能耗较高的问题;真空感应熔炼可显著降低氧、氮含量,但对已形成的夹杂物去除效果一般;泡沫陶瓷过滤对微米级夹杂物有良好拦截效果,但属于消耗性工艺;电子束熔炼净化效果优异但设备复杂且能耗巨大;底吹气泡浮选对小尺寸夹杂物去除效率高,但工艺稳定性有待提升。未来,废旧高温合金回收的研究应着重于开发高效低耗的新型复合净化工艺,提升工艺的连续性和自动化水平,同时建议建立完善的废料回收体系。

    Abstract:

    Superalloys have been widely used in aerospace, aviation, energy and other high-end manufacturing industries. A large amount of waste superalloys are produced every year. The purification and regeneration technology of waste superalloys is of great significance to promote the healthy development of Chinas high-tech industry. Research indicates that inclusions insuperalloys alloys primarily originate from chemical reactions during the melting process, elemental contamination from service environments, and foreign impurities introduced during processing and storage. These inclusions can be categorized into various types such as oxides, sulfides, and nitrides based on their composition and morphology. The presence of these inclusions significantly degrades the mechanical performance, corrosion resistance, and fatigue life of materials, potentially leading to failure in critical components.In response to this issue, this paper focuses on a comparative analysis of the advantages and disadvantages of six mainstream purification processes, including mechanical grinding, electroslag remelting, vacuum induction melting, foam ceramic filtration, electron beam melting, and bottom-blown bubble flotation technology. Among these methods, mechanical grinding is suitable for the removal of surface inclusions; it is cost-effective but has limited processing depth. Electroslag remelting can effectively eliminate large-sized inclusions; however, it poses challenges due to high energy consumption. Vacuum induction melting significantly reduces oxygen and nitrogen content but generally shows moderate effectiveness in removing already formed inclusions. Foam ceramic filtration demonstrates excellent interception capabilities for micron-sized inclusions but is classified as a consumable process. Electron beam melting offers outstanding purification results yet involves complex equipment and substantial energy requirements. Lastly, bottom-blown bubble flotation exhibits high efficiency in removing small-sized inclusions; nevertheless, its process stability requires further improvement. In the future, the research on the recovery of waste superalloys should focus on the development of new composite purification processes with high efficiency and low consumption, improve the continuity and automation level of the process, and suggest the establishment of a sound waste recovery system.

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展开, 李帅, 郑永兴, 等.废旧高温合金夹杂物的产生及净化工艺研究进展[J].中国有色冶金,2025,54(3):1-13.

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  • 收稿日期:2024-09-26
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  • 在线发布日期: 2025-12-18
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