废弃钕铁硼磁体稀土元素回收工艺研究现状及展望
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作者单位:

1.东北大学 多金属共生矿生态化冶金教育部重点实验室, 辽宁 沈阳 110819 ;2.东北大学 冶金学院, 辽宁 沈阳 110819

作者简介:

董静静(1998—),女,山东菏泽人,硕士研究生,研究方向为稀土资源回收。

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中图分类号:

TF125.2+4;TF845

基金项目:

国家自然科学基金青年科学基金项目(No.52204310);中央高校基本科研业务费专项资金(N2125010)


Review and perspective of rare earth element recovery process for scrap NdFeB magnets
Author:
Affiliation:

1.Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education), Northeastern University, Shenyang 110819 , China ; 2.School of Metallurgy, Northeastern University, Shenyang 110819 , China

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    摘要:

    本文以典型钕铁硼磁体的成分及物相特征为基础,阐述了国内外钕铁硼废料回收工艺的发展现状,其中,直接回收工艺能耗低、环境友好,但其仅适用于结构保存相对完整的钕铁硼磁体废料;湿法工艺可以有效提取钕铁硼磁体废料中的稀土和铁等元素,但流程相对复杂、耗酸量大,且会产生二次废酸废碱;火法回收工艺流程短,适合大规模操作,但存在耗能高,稀土元素回收率相对较低的问题;联合工艺克服了湿法和火法工艺的缺点,具有较好的应用前景。未来钕铁硼回收工艺的开发应着重解决现行技术存在的资源环境污染等问题,同时也应加大基础相变热力学数据库及有价金属微观迁移动力学模型的建立,兼顾非稀土金属的循环高值利用,促进钕铁硼回收产业朝着绿色化、低成本、短流程、高收率的方向发展。

    Abstract:

    Based on the composition and phase characteristics of typical NdFeB magnets, this paper elaborates on the current development status of NdFeB waste recycling processes domestically and internationally. Among these, direct recycling processes demonstrate low energy consumption and environmental friendliness, but they are only applicable to NdFeB magnet waste with relatively intact structures. Hydrometallurgical processes can effectively extract elements such as rare earths and iron from NdFeB magnet waste, yet they involve relatively complex procedures, high acid consumption, and generate secondary acidic and alkaline waste. Pyrometallurgical recycling offers shorter process flows suitable for large-scale operations but suffers from high energy consumption and relatively low rare earth element recovery rates. Hybrid processes overcome the shortcomings of both hydrometallurgical and pyrometallurgical methods, showing promising application prospects. Future development of NdFeB recycling technologies should focus on addressing existing issues such as resource and environmental pollution while strengthening the establishment of fundamental phase transformation thermodynamics databases and microscopic migration kinetics models for valuable metals. Concurrent efforts should prioritize the high-value recycling of non-rare earth metals, driving the NdFeB recycling industry toward greener, lower-cost, shorter-process, and higher-yield development directions.

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董静静, 石俊杰, 邱玉超, 等. 废弃钕铁硼磁体稀土元素回收工艺研究现状及展望[J].中国有色冶金,2025,54(1):30-41.

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  • 收稿日期:2024-08-10
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  • 在线发布日期: 2025-12-18
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