铝工业赤泥用于脱硫技术现状及展望
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作者单位:

1.中铝环保节能集团有限公司, 北京 101300 ; 2.中铝环保节能集团有限公司北京技术中心, 北京 101300 ;3.北京铝能清新环境技术有限公司, 北京 101300

作者简介:

闫飞飞(1992—),男,山西吕梁人,研究员,主要从事有色金属行业环保技术研究。

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中图分类号:

X758;TF111.14

基金项目:

中央引导地方科技发展资金项目(高炉煤气精脱硫工业化应用示范项目226Z3702G);黄河流域生态保护和高质量发展联合研究(2022-YRUC-01-0302)


Current situation and prospect of red mud for desulfurization technology
Author:
Affiliation:

1.Environmental Protection and Energy Conservation Group Co.Ltd., CHINALCO, Beijing 101300 ;2.Beijing Technical Center of Chinalco Environment and Energy Conservation Co.Ltd., Beijing 101300 ;3.Beijing Aluminum Fresh Environmental Technology Co.Ltd., Beijing 102300

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    摘要:

    以铝工业赤泥作为原料制备工业脱硫剂,具有来源丰富、价格低廉、理论硫容高等优点,在低成本脱硫的同时,达到了“以废制废”的目的。本文总结了铝工业赤泥在脱硫方面的应用,全面综述了赤泥干法、湿法脱除SO2和H2S的技术现状,从活性组分利用效率、能量消耗、工艺复杂程度、后续环境问题等几个维度分析对比了几种研究方向各自的优劣,并展望了未来工业化应用可能遇到的问题和进一步研究方向。指出在湿法浆液脱除烟气中SO2方面,仍需克服管道堵塞、低效率、高能耗、以及由此产生的大量稀盐处理等技术性难题,同时应对其含有的过渡金属的反应机理和活化手段进行研究;在干法脱除H2S方面,需进一步从低成本活化氧化铁的途径、极端工况环境下的适用性、废脱硫剂的资源化、以及与其他工业固废的协同处理等方面展开研究。

    Abstract:

    As an industrial desulfurizer, aluminum industrial red mud has the advantages of abundant source, low price and high overall sulfur capacity. It achieves the purpose of “waste to waste” while desulfurizing at low cost. In this paper, the application of aluminum industrial red mud in flue gas desulfurization was summarized, and the research progress of dry and wet red mud removal SO2 and H2S in flue gas was comprehensively reviewed. The advantages and disadvantages of several research directions were compared and analyzed from several dimensions, such as utilization efficiency of active components, energy consumption, complexity of process and subsequent environmental problems. The possible problems and further research directions of market application in the future are also prospected. It is pointed out that in the SO2 removal from flue gas by wet grout process, it is still necessary to overcome the technical problems such as pipeline blockage, low efficiency, high energy consumption, and the resulting large amount of dilute salt treatment. At the same time, the reaction mechanism and activation means of the transition metals contained in it should be studied. In terms of dry removal of H2S, further research should be carried out from the aspects of low-cost activated iron oxide, applicability in extreme environment, recycling of waste desulfurizer, and collaborative treatment with other industrial solid wastes.

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闫飞飞,刘万超,练以诚,等. 铝工业赤泥用于脱硫技术现状及展望[J]. 中国有色冶金, 2024, 53(2):34-41.

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  • 收稿日期:2023-10-22
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  • 在线发布日期: 2025-12-21
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