含钛高炉渣钛回收技术及专利分析
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作者单位:

国家知识产权局专利局, 北京 102206

作者简介:

王妤(1977—),江西吉安人,硕士,二级调研员,主要从事冶金领域专利审查工作。

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中图分类号:

TF534.2;TF823

基金项目:


The titanium recovery technology and patent analysis of titanium bearing blast furnace slag
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China National Intellectual Property Administration, Beijing 102206 , China

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    摘要:

    国内每年产生约400万t的含钛高炉渣,目前堆存量已超过8000万t,攀西地区含钛高炉渣中TiO2含量大于20%,具有较高钛资源利用价值,现有提取钛产品主要包括3个技术分支:制备TiO2,制备TiC/TiCl4以及制备钛合金。本文对上述技术分支及应用现状进行了介绍,并从专利角度分析了各技术分支的专利申请量、申请人类型、主要申请人、国际专利分类号及专利文献的被引证次数,在此基础上,对未来含钛高炉渣的提钛技术发展进行了研判:提钛制品为TiO2的技术研发仍是未来的重点,主流工艺技术为选择性析出分离提钛以及酸浸水解湿法冶金提钛,研究方向为通过改善分离或酸浸或水解工艺,以提高提钛效率、降低酸耗和减轻对环境的污染;提钛制品为TiC/TiCl4的技术将以高温还原为基础,并以钛转化率(即碳化率)和生产效率的提高为目标开展研究;提钛制品为钛或钛合金的技术则需要通过改变还原剂或者改进工艺生产金属钛或拓宽钛合金的产品范围。

    Abstract:

    About 4 million tons of titanium-bearing blast furnace slag is produced domestically each year, and currently stockpiles have been exceeded 80 million tons. TiO2 content in the titanium-bearing high slag from west region of Panzhihua is greater than 20% and has higher utilization value. Currently extracted titanium products mainly include the following several technical branches: the preparation of TiO2, the preparation of TiC/TiCI4 and the preparation of titanium alloys. Technical introduction and state of application of the three technical branches are described herein. Patent application, applicant type, the main applicant, international patent classification and cited times are analyzed from the patent perspective. On this basis, research and judgment of the future development of titanium extraction technology on the titanium bearing blast furnace slag are made. The technical research on the Ti-extracting product with TiO2 will be the focus in the future, technology of Ti-extracting by selective precipitation separation or by acid soak hydrolysis hydrometallurgy will be the main process technology, and improving efficiency of Ti-extracting, or reducing acid consumption or pollution on environment by improving process of separation, acid leaching or hydrolysis will be the main direction of researching; The technical research on the Ti-extracting product with TiC/TiCl4 will be based on high temperature reduction, and will be purposed on improving titanium conversion efficiency and production efficiency. The technical research on the Ti-extracting product with Ti alloy will be focused on changing reducing agent, improving process of producing metal Ti, or widening the product range of Ti alloy.

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王妤. 含钛高炉渣钛回收技术及专利分析[J]. 中国有色冶金, 2023, 52(4): 25-33.

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  • 收稿日期:2023-01-26
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  • 在线发布日期: 2025-12-23
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