钢渣碳化及其对水泥砂浆性能影响的试验研究
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国网江苏省电力有限公司南京供电分公司, 江苏 南京 210000

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栾宁(1978—),男,江苏南京人,硕士,高级工程师,主要从事碳排放管理、碳捕集与利用、营销管理、信息化建设研究方面的工作。

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TF4;X756

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国家电网有限公司科技项目资助(J2021192)


Experimental study on carbonation of steel slag and its influence on the properties of cement mortar
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State Grid Nanjing Power Supply Company, Nanjing 210000 , China

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    摘要:

    冶金工业和水泥工业是全球CO2排放的主要行业,面临着巨大的“碳减排”挑战。钢渣是冶金工业产生的大宗固体废弃物,在富CO2的环境下具有较高的碳化反应活性。本文以钢渣为主要原料,研究钢渣在常温常压下的碳捕集能力,制备了用于水泥行业的碳化钢渣掺合料,并探索了其对水泥砂浆流动度、力学强度和微结构的影响。结果表明,钢渣可在常温常压下捕集CO2,钢渣的碳化增重最高可达9.11%,表明每吨钢渣可捕集约90kg CO2;经过碳化处理的钢渣由于表面形成了多孔碳化产物,吸水率会增加,因此会对水泥砂浆的流动度有一定的影响;掺有碳化钢渣的水泥基材料结构更为致密,水泥砂浆后期力学强度优于掺有未碳化钢渣的水泥基材料,并且碳化增重率越高,水泥砂浆的28d抗压强度也越高。

    Abstract:

    Metallurgical and cement industries were the main industries of CO2 emission in the world, and has been faced a huge challenge of “carbon emission reduction”. Steel slag, a solid waste produced by metallurgical industry, has high carbonation reactivity into a CO2 rich environment. In this paper, the CO2 capturing capacity of steel slag under room temperature and atmospheric pressure was explored. Carbonated steel slag admixture for cement industry was prepared. And its influences on the fluidity, mechanical properties and microstructures of cement-based materials were investigated. The results showed that the carbonation weight gain of steel slag could reach 9.11%, indicating that about 90kg CO2 could be captured by per ton of steel slag. Due to the porous microstructures of carbonated steel slag, the water absorption rate was increased, which had a certain impact on the fluidity of cement mortar. The mechanical strength of cement mortars mixed with carbonated steel slag was better than that of mixed with non-carbonated steel slag, and the higher the carbonation weight gain, the higher the 28d compressive strength of cement mortar.

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栾宁,殷鸣,陈堃,等.钢渣碳化及其对水泥砂浆性能影响的试验研究[J]. 中国有色冶金, 2023, 52(1): 107-113.

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  • 收稿日期:2022-07-23
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  • 在线发布日期: 2025-12-23
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