ChClureaZnO低共熔溶剂体系的物理性质研究
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苏州大学沙钢钢铁学院, 江苏 苏州 215021

作者简介:

顾鹏伟(1997—),男,江苏丹阳人,硕士研究生,主要从事冶金资源综合利用方面的研究。

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中图分类号:

TF813

基金项目:

国家自然科学基金项目(51704201);省部共建高品质特殊钢冶金与制备国家重点实验室、上海市钢铁冶金新技术开发应用重点实验室开放课题(SKLASS 2019-10);上海市科学技术委员会资助课题(19DZ2270200)


Physical properties of ChClureaZnO eutectic solvent system
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School of Iron and Steel, Soochow University, Suzhou 215021 , China

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    摘要:

    ChClurea体系中ZnO的溶解度较大,可实现ZnO的选择性溶解和有效分离,ChClureaZnO体系物理性质对ZnO的溶解度影响较大,进而影响ZnO的分离提取过程。在323~363K温度范围内,分别测定ChClureaZnO体系的黏度、电导率、密度和表面张力,研究温度和ZnO浓度对其物理性质的影响。结果表明,在所研究的温度范围内, ChClureaZnO体系黏度为20~200mPa·s,电导率为0.2~0.8S·m-1,密度约为1.20g·cm3,表面张力在50~80mN·m-1;体系黏度随着温度升高而降低,电导率随着温度的增加而增大,电导率与黏度之间关系满足Walden规则;密度和表面张力均随着温度升高而逐步减小;ChClureaZnO低共熔溶剂的黏度、电导率、密度和表面张力均随着体系中ZnO浓度的增大而增加。

    Abstract:

    The solubility of ZnO in the system of ChClurea is high, which makes it possible to realize selective dissolution and effective separation of ZnO, the physical properties of ChClureaZnO system impose large impact on the solubility of ZnO, while the solubility of ZnO has remarkable influence on the separation and extraction process. Within the temperature range of 323~363K, the viscosity, conductivity, density and surface tension of the ChClureaZnO system are measured respectively, and the impact of temperature and ZnO concentration on its physical properties is studied. The result shows that within the temperature range of 323~363K, the viscosity of the ChClureaZnO system is 20~200mPa·s, conductivity 0.2~0.8S/m, density about 1.20g·cm3 and surface tension 50~80mN/m; with the temperature rise, the viscosity of the system becomes lower, the conductivity becomes higher, and the relationship between the conductivity and viscosity meet the Walden law; the density and surface tension gradually get lower with the temperature rise; the viscosity, conductivity, density and surface tension of the ChClureaZnO eutectic solvent increase with the increase of the ZnO concentration in the system.

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顾鹏伟,施森杰,许继芳,等. ChClureaZnO低共熔溶剂体系的物理性质研究[J].中国有色冶金, 2022, 51(2): 119-124.

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  • 收稿日期:2021-10-25
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  • 在线发布日期: 2025-12-24
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