锌氧压浸出硫回收率影响因素分析及提升措施
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西部矿业股份有限公司锌业分公司, 青海 西宁 811600

作者简介:

杨泽(1989—),男,甘肃武威人,冶金工程师,主要从事湿法炼锌生产技术管理工作。

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TF803

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Analysis on factors influencing sulfur recovery in zinc pressure oxidative leaching and improvement measures
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Zinc Industry Branch of Western Mining Co., Ltd.,Xining 811600 , China

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    摘要:

    锌氧压浸出工艺最大优势在于副产品是固体硫磺而非硫酸,可以从根本上解决传统工艺带来的硫酸滞销问题和SO2污染。某锌冶炼企业采用锌氧压浸出工艺,在初期进行硫回收工序时,硫磺产量低,大部分的硫未得到有效回收,进入尾矿渣中,造成硫损失和尾渣处理难度大的问题。该企业系统分析了氧压浸出工艺过程,通过控制工艺参数和提高二段浸出渣中硫精矿的粒度提高了氧压浸出过程中的硫转化率,通过控制矿浆浓度、矿浆粒度、浮选槽风量等提高了浮选过程中的硫回收率,通过规范过滤操作、保障熔硫池温度等措施提高了后续工序的硫回收率。该企业采取改进措施以后,总硫回收率从45%提高至71%,可为同类企业提高硫回收率提供参考。

    Abstract:

    The biggest advantage of the zinc pressure oxidative leaching process is that the byproduct is solid sulfur instead of sulfuric acid, which can fundamentally solve the problems of slow sales of sulfuric acid and SO2 pollution caused by traditional processes. A zinc company utilized the zinc pressure oxidative leaching process in its production. When the sulfur recovery process was carried out in the initial stage, the sulfur recovery was low, with most of the sulfur having not been effectively recovered but brought to the tailings, resulting in the loss of sulfur and the difficulty of tailings treatment. Subsequently, the company systematically analyzed the pressure oxidative leaching process, and improved the sulfur conversion rate during the pressure oxidative leaching process by regulating the process parameters and increasing the particle size of the sulfur concentrate in the secondstage leaching residue, and improved the sulfur recovery rate in the flotation process by controlling the slurry concentration, slurry particle size, and air volume of the flotation cells, and increased the sulfur recovery rate in the subsequent procedures by standardizing the filtration operation and ensuring the temperature of the molten sulfur tank. After the company took such improvement measures, the total sulfur recovery rate increased from 45% to 71%. The specific methods can provide reference for other similar enterprises to improve their sulfur recovery rate.

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杨泽, 解万文, 沈强, 等. 锌氧压浸出硫回收率影响因素分析及提升措施[J]. 中国有色冶金, 2022, 51(2): 50-53,60.

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  • 收稿日期:2021-11-02
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  • 在线发布日期: 2025-12-24
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