含碲物料碱浸提取碲的试验探索
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1.大冶有色金属有限责任公司, 湖北 黄石 435002 ;2.有色金属冶金与循环利用湖北省重点实验室, 湖北 黄石 435002

作者简介:

房孟钊(1988—),男,汉族,河南荥阳人,硕士,冶金工程师,主要从事有色金属冶金及稀贵金属湿法冶金技术开发与应用方面的研究工作。

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TF811;TF803.2

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Exploratory test on tellurium extraction from tellurium-bearing materials by alkaline leaching
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    摘要:

    为探索铜阳极泥流程短、操作简便、损耗低、回收率高的碲回收工艺,本文对其处理过程中的四种含碲物料进行了直接或间接的碱浸试验,并对最终较优碱浸工艺的产物进行了除杂试验,得到如下结论:对蒸硒渣进行直接或间接碱浸试验,碲的浸出率为1.26%,蒸硒渣中正四价碲含量很低;对沉金后液中和渣进行碱浸试验,碲的浸出率为1.2%,沉金后液中的碲主要是正六价碲;对铂钯精矿直接或间接碱浸试验,碲的浸出率不超20%,铂钯精矿中有少部分的正四价碲,主要是单质碲、正六价碲;对一次还原后液中和渣进行直接碱浸试验,碲的浸出率达到98.69%,中和渣中碲的形态主要是正四价碲;采用Na2S对碱浸液中的重金属除杂,效果较好。

    Abstract:

    In order to explore the process of recovering tellurium from copper anode slime, which features short process flow, simple operation, low Te loss and high Te recovery, direct or indirect alkaline leaching tests are carried out for four kinds of Te bearing materials produced in the processing of copper anode slime, and impurity removal test is carried out for the product from the leaching process with higher Te recovery. The following conclusions are drawn: Te leaching rate reports 1.26% at most in the alkaline leaching test for selenium-removed residue, which contains a small amount of Te4+; that is 1.2% in the alkaline leaching test for the neutralization residue of the solution resulting from Au precipitation, in the solution Te exists mainly in the form of Te6+; that is no more than 20% in the alkaline leaching test for Pt-Pd concentrate, which contains elemental tellurium and Te6+ mostly and small amount of Te4+; while the leaching rate of Te can reach 98.69% in the alkaline leaching test for the neutralization residue of the solution from primary reduction, in the residue Te exists in the form of Te4+, and Na2S is used to remove the heavy metals in the leachate, showing good effect.

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房孟钊.含碲物料碱浸提取碲的试验探索[J].中国有色冶金,2021,50(5): 73-75.

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  • 收稿日期:2021-03-16
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  • 在线发布日期: 2025-12-24
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