降低冶炼废水COD的生产实践
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阳谷祥光铜业有限公司, 山东 阳谷 252327

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冯芝勇(1987—),山东聊城人,硕士,从事铜冶炼制酸工艺方面的技术及管理工作。

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X758

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Production practice of reducing COD in smelting wastewater
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    摘要:

    针对冶炼废水中COD值高的问题,祥光铜业从废水来源、控制流程和管控措施三个方面进行排查治理废酸污水的COD指标,采取以下措施来降低废水COD值:净化加酸,提高硫酸浓度在4%以上;通过技术改造和定期检查清理,保证脱吸塔的脱吸效果和中和氧化曝气效果;脱吸循环液和硫化滤液添加脱硫双氧水循环液,初步降低废水COD指标;电石渣中和工序添加脱硫双氧水循环液,进一步降低废水COD值。经过改造后,最终外排水COD值可以控制在30~40mg/L,稳定达标排放。

    Abstract:

    On account of the high COD level in smelting wastewater, Xiangguang Copper has made a check from three aspects, i.e., source of wastewater, production process control procedure and production management measures, for control of the COD index in acidic wastewater. The following measures have been taken to reduce COD in wastewater: sulfuric acid concentration is increased to above 4% for purification; technical upgrade and regular inspection and cleaning are carried out to ensure the desorption effect of desorption tower and neutralization-oxidation-aeration effect; hydrogen peroxide circulating solution is added into the desorption circulating solution and sulfide filtrate to preliminarily reduce the COD level in wastewater; hydrogen peroxide circulating solution is added in the carbide slag neutralization process to further reduce the COD level in wastewater. As a result, the COD in the wastewater is controlled within 30~40mg/L, meeting the discharge standard.

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冯芝勇, 曹汝俊, 邱远鹏, 等. 降低冶炼废水COD的生产实践[J]. 中国有色冶金, 2021, 50(4): 108-111.

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  • 收稿日期:2020-12-29
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  • 在线发布日期: 2025-12-24
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