硫化沉砷-石膏中和工艺处理铜冶炼废酸污水的生产实践
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阳谷祥光铜业有限公司, 山东 阳谷 252327

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冯芝勇(1987—),山东聊城人,硕士,从事铜冶炼制酸工艺方面的技术及管理工作。

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TF811;X758

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Production practice of vulcanization precipitating arsenic and gypsum neutralization process for treatment of acid sewage waterfrom copper smelting
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    摘要:

    阳谷祥光铜业有限公司采用硫化沉砷-石膏中和工艺处理烟气制酸产出的废酸污水,处理过程中会有硫化氢、二氧化碳等气体产生,需要处理系统进行吸收,保证无组织气体(硫化氢、二氧化碳)零排放。硫化沉砷工序一段除害塔的硫化氢不能被完全吸收,通过将一段除害塔出口管道接入二段除害塔风机进口可以将其吸收完全,吸收液可作为硫化氢反应液循环使用;石膏中和工序产生的无组织气体包括硫化氢和二氧化碳,经过两次碱液喷淋洗涤系统改造使得石膏生产中无组织气体得到有效控制,通过提高反应槽抽气及负压效果、改进反应槽进液管位置、在反应槽底部增设自循环隔膜泵等措施,减缓了反应淤槽和堵料情况,使得石膏风机抽气管路畅通,保证了抽气效果。

    Abstract:

    Yanggu Xiangguang Copper Industry Co., Ltd. uses vulcanization precipitating arsenic-gypsum neutralization process to treat acid sewage water from flue gas sulphuric acid production.During the treatment process, gases such as hydrogen sulfide and carbon dioxide are generated, which need to be absorbed by the treatment system to ensure zero emission of fugitive gases.The hydrogen sulfide in the first stage of the detoxification tower in the vulcanization precipitating arsenic process cannot be completely absorbed. It can be completely absorbed by connecting the outlet pipe of the first stage of the detoxification tower to the fan inlet of the second stage of the detoxification tower, and the absorption liquid can be recycled as the hydrogen sulfide reaction liquid.The unorganized gas generated in the gypsum neutralization process includes hydrogen sulfide and carbon dioxide. After two lye spray washing system transformations, the unorganized gas in the gypsum production can be effectively controlled. The reaction tank is improved by improving the gas extraction and negative pressure effects of the reaction tank.Measures such as the location of the liquid inlet pipe and the addition of a self-circulating diaphragm pump at the bottom of the reaction tank slowed down the reaction siltation tank and blockage, so that the gypsum fan’s air extraction pipeline was unblocked and the air extraction effect was ensured.

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冯芝勇,邱远鹏,曹汝俊,等.硫化沉砷-石膏中和工艺处理铜冶炼废酸污水的生产实践[J].中国有色冶金,2021,50(3): 75-78.

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  • 收稿日期:2020-11-24
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  • 在线发布日期: 2025-12-24
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