离子交换树脂在红土镍矿湿法冶炼中的应用:被吸附溶液pH值和树脂再生性能研究
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中国恩菲工程技术有限公司, 北京 100038

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林洁媛(1985—),女,汉族,福建福州人,博士,中国恩菲研发工程师,研究方向为矿物湿法冶金过程中多金属复杂溶液体系的高效分离工艺开发和过程强化,主要包括红土镍矿、盐湖卤水。

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TF815;TF804.2;TF804.3

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Application of ion exchange resin in laterite nickel ore hydrometallurgy: study on the pH value of adsorbed solution and theresin regeneration performance
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    摘要:

    离子交换树脂吸附技术在回收红土镍矿浸出液中镍、钴的应用方面还处于研究阶段,前期研究结果表明该技术可行,并给出了相应的工艺条件。本文在之前实验研究基础上,针对液相初始pH值优选范围是pH≥3的结论和树脂再生的条件和性能进行了进一步的实验,得出了更为成熟的结论。pH值对树脂吸附各金属容量影响的实验表明,将被吸附溶液pH值调节到4,再实施吸附工序较为合适;氢氧化钠浓度对树脂的再生性能影响的实验表明,先用硫酸解吸,再用氢氧化钠溶液转型可以实现树脂再生,采用的转型液氢氧化钠浓度为5%合适;树脂的再生性能检测实验表明,实验中采用的树脂经过多次再生后对溶液的镍、钴的吸附容量没有明显下降。

    Abstract:

    The application of ion exchange resin adsorption technology in the recovery of nickel and cobalt in laterite nickel ore leaching solution is still in the research stage. The previous research results showed that the technology is feasible, and the corresponding process conditions were given.Based on the previous experimental research, this article conducted further experiments based on the previous conclusion that the initial pH value of the liquid phase is pH≥3, and the conditions and performance of resin regeneration, and reached a more mature conclusion.Experiments on the influence of pH value on the adsorbcapacity of the resin for each metal show that it is more appropriate to adjust the pH value of the adsorbed solution to 4 before implementing the adsorption process. The experiment of the influence of sodium hydroxide concentration on the regeneration performance of the resin shows that the resin regeneration can be achieved by first desorption with sulfuric acid and then transformation with sodium hydroxide solution. The sodium hydroxide concentration of the transformation solution used is 5%.The resin regeneration performance test experiment showed that the resin used in the experiment did not significantly decrease the adsorption capacity of the solution for nickel and cobalt after repeated regeneration.

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林洁媛,刘诚,李勇,丁剑,陆业大,孙宁磊.离子交换树脂在红土镍矿湿法冶炼中的应用:被吸附溶液pH值和树脂再生性能研究[J].中国有色冶金,2021,50(1):76-80

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  • 收稿日期:2020-05-20
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  • 在线发布日期: 2025-12-24
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