回转窖尾气氧化锌脱硫技术及其应用
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中金岭南有色金属股份有限公司丹霞冶炼厂, 广东 韶关 512000

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邓学广(1967—),男,广西富川人,本科,高级工程师,长期从事技术研究和生产组织管理工作。

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TF813;TF805.3;X758

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Zinc oxide desulfurization technology for rotary kilin flue gas and its application
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    摘要:

    某冶炼厂采用回转窑回收锌氧压浸出液针铁矿除铁产出铁渣中的氧化锌,原来采用传统的钙法脱硫工艺处理回转窑烟气,存在脱硫效果差、排放尾气不达标、石膏渣难处置、开工率低等问题。经多方考证后,决定改用氧化锌脱硫工艺进行处理,脱硫剂采用自产氧化锌烟尘或焙砂,产出的二氧化硫返回制酸系统,酸解液返电锌系统,不产生二次固体废物。新系统投产后,运行稳定,增加了企业经济效益,而且排放尾气指标优于国家标准要求。本文对该技术的工艺流程、工艺参数及设备进行了详细介绍,并对生产实践中应该注意的问题进行了总结和说明。

    Abstract:

    A smelting company used a rotary kiln process to recover zinc oxide from the iron slag in hydrometallurgical zinc process, and originally used the traditional calcium desulfurization process to treat the flue gas from rotary kiln, which had the problems such as poor desulfurization effect, substandard exhaust gas, difficult disposal of gypsum slag, and low operating rate. After many verifications, the company decided to switch to zinc oxide-acid desulfurization process. The desulfurization agent adopts self-produced zinc oxide fume or calcine. The sulfur dioxide produced is returned to the acid production system, and the acid hydrolysis liquid is returned to the zinc system. The system does not produce secondary solid waste. After the new system was put into production, the operation was stable, which increased the economic benefits of the enterprise, and the exhaust emission index was better than the national standard. This article introduces the technological process, technological parameters and equipment of the modified technology in detail, and summarizes and explains the problems that should be paid attention to in production practice.

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邓学广.回转窖尾气氧化锌脱硫技术及其应用[J].中国有色冶金,2021,50(1):49-52

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  • 收稿日期:2020-07-10
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  • 在线发布日期: 2025-12-24
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