Research advances in CO2 carbonation technology for synthesis of crystalline carbonates
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1.School of Rare Earth, University of Science and Technology of China, Hefei 230026 , China ; 2.Institute of Resources and Ecological Environment, Ganjiang Innovation Research Institute, Chinese Academy of Sciences, Ganzhou 341119 , China ;3.State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190 , China ;4.Research Center for Materials and Optoelectronics, University of Chinese Academy of Sciences, Beijing 100049 , China ;5.School of metallurgical engineering, Jiangxi University of Science and Technology, Ganzhou 341000 ,China

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TF80

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    Abstract:

    Crystalline carbonates, characterized by their distinctive morphologies and narrow particle size distributions, hold significant applications in fields such as ink manufacturing, electronics, and military technologies. Carbonation methods have emerged as a critical process for synthesizing crystalline carbonates due to their simplicity, controllability, low cost, and ability to produce metal compounds with tailored physical properties. This review systematically outlines existing carbonation technologies, categorizing them into direct bubbling and microbubble-enhanced methods based on CO2 introduction strategies. Key factors influencing the carbonation process are elaborated, including carbonation temperature, CO2 flow rate and concentration, solution concentration, additives, stirring speed, and pH values. Furthermore, the review highlights typical applications of carbonation techniques, such as the preparation of calcium carbonate, nano-silica, basic magnesium carbonate, and rare-earth carbonates. Finally, future prospects and trends in carbonation-based synthesis of crystalline carbonates are discussed.

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阳欢,汪哲平,王灵岘,等. CO2碳化制备晶型碳酸盐技术研究进展[J].有色设备,2025,39(2):10-25.

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  • Received:February 10,2025
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  • Online: November 13,2025
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