In recent years, with the rise of green energy, lithium-air batteries have become a research hotspot due to their high energy density and environmental protection characteristics. Among them, the energy density of a lithium-air battery using a non-aqueous electrolyte system is about 11420Wh/kg, which is almost equal to the energy density of gasoline, which makes lithium-air batteries have great application potential in electric vehicles and other aspects. This article introduces the application of non-aqueous electrolytes in lithium-air batteries from five aspects: carbonate-based electrolytes, ether-based electrolytes, sulfur-containing electrolytes, ionic liquid-based electrolytes, and electrolyte salts. Provide help for the follow-up study of non-aqueous electrolyte in lithium-air batteries.