钼冶炼工艺发展现状及展望
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作者单位:

1.中南大学 冶金与环境学院, 湖南 长沙 410083 ;2.稀有金属冶金与材料制备湖南省重点实验室, 湖南 长沙 410083

作者简介:

陈志远(2000—),男,山东德州人,在读博士,主要研究方向为有色金属冶金。

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中图分类号:

TF841.2

基金项目:

国家自然科学基金面上项目(52174340),国家重点研发计划项目 (2022YFC2904505)、芙蓉学者计划


Current development status of molybdenum smelting technology
Author:
Affiliation:

1.School of Metallurgy and Environment, Central South University, Changsha 410083 , China ;2.Hunan Provincial Key Laboratory of Rare Metal Metallurgy and Materials Preparation, Changsha 410083 , China

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    摘要:

    钼是一种重要的战略稀有金属,广泛应用于钢铁、化工、航空航天等领域。辉钼矿是最重要的钼冶炼原料,其氧化焙烧工艺一直是国内外主流的工艺。焙烧得到的氧化钼主要用作钢铁行业的添加剂,也是生产钼铁的和钼酸铵化工产品的主要原料。随着优质辉钼矿资源的日益消耗,低品位的复杂辉钼矿所占比重越来越大,传统工艺面临着烟气治理难、综合收率低等诸多问题。为此,本文归纳了近些年开展的辉钼矿冶炼工艺研究,如加助剂焙烧工艺、氯化工艺、直接还原工艺和真空热分解工艺等火法工艺、硝酸常压氧化法、次氯酸钠分解法、酸碱介质氧压分解法和电氧化分解等湿法工艺,分析对比了各工艺的特点,展望了未来钼冶金的主要发展方向。

    Abstract:

    Molybdenum is an important strategic rare metal, widely used in steel, chemical, aerospace and other fields. Molybdenite is the most important raw material for molybdenum smelting, and its oxidation roasting process has always been the mainstream process in China and other countries. The molybdenum oxide obtained by roasting is mainly used as an additive in the steel industry and is also the main raw material for the production of ferromolybdenum and ammonium molybdate chemical products. With the increasing consumption of high-quality molybdenite resources, the proportion of low-grade complex molybdenite is getting larger and larger, and the traditional process is facing many problems such as difficult flue gas treatment and low comprehensive recovery rate. Therefore, this paper summarizes the research on molybdenite smelting processes carried out in recent years, such as the addition of additives for roasting, chlorination process, direct reduction process and vacuum thermal decomposition process, nitric acid atmospheric oxidation method, sodium hypochlorite decomposition method, acid-base medium oxygen pressure decomposition method and electro-oxidation decomposition method, analyzes and compares the characteristics of each process, and looks forward to the main development directions of molybdenum metallurgy in the future.

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引用本文

陈志远,江紫辉,胡遒,等.钼冶炼工艺发展现状及展望[J].有色设备,2025,39(6):10-23.

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  • 收稿日期:2025-10-28
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  • 在线发布日期: 2026-02-13
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