铜/铝异种金属扩散焊接头耐腐蚀性能研究
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作者单位:

1.辽宁科技大学 机械工程与自动化学院, 辽宁 鞍山 114051 ; 2.辽宁省复杂工件表面特种加工重点实验室, 辽宁 鞍山 114051 ;3.崇义章源钨业股份有限公司, 江西 赣州 341000

作者简介:

田继鹏(2002—),男,辽宁大连人,硕士研究生,主要研究方向为异种金属连接技术。

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中图分类号:

TG453.9

基金项目:

辽宁省教育厅高校基本科研项目(LJ212410146074)


Study on corrosion resistance of copper/aluminum dissimilar metal diffusion welding joints
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Affiliation:

1.School of Mechanical Engineering and Automation, University of Science and Technology Liaoning, Anshan 114051 ,China ;2.Liaoning Key Laboratory of Special Machining for Complex Workpiece Surface, Anshan 114051 ,China ; 3.Chongyi Zhangyuan Tungsten Co., Ltd,Ganzhou 341000 ,China

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    摘要:

    本研究采用真空扩散焊接工艺焊接T2Cu和1060Al,使用扫描电子显微镜(SEM)和能量色散光谱仪(EDS)分析扩散层的微观结构和物相组成,在3.5wt%NaCl溶液中进行腐蚀浸泡试验和电化学腐蚀性能研究,分析比较了每个扩散层和基材的耐腐蚀性。结果表明,在T2Cu/1060Al真空扩散接头的界面处形成了由AlCu层、Al2Cu层、Al4Cu9层组成的扩散层。扩散层不同区域的耐腐蚀性存在差异,铜侧扩散层区域腐蚀程度相对较轻,铝侧扩散层区域从点蚀孔发展成点蚀坑,随着时间的延长形成了不规则的深沟壑,最终发展成为剥落腐蚀。基材及各个扩散层按耐腐蚀性强弱排序为:T2Cu>Al4Cu9>AlCu>Al2Cu>1060Al。

    Abstract:

    In the study, the vacuum diffusion welding process was used to successfully weld T2 copper and 1060Al. The scanning electron microscope and energy dispersive spectrometer were utilized to analyze the microstructure and phase composition of the diffusion layer. Corrosion immersion tests and research on the electrochemical corrosion performance were carried out in a 3.5wt%NaCl solution to study and compare the corrosion resistance of each diffusion layer and the base materials. The results show that a diffusion layer composed of the AlCu layer, Al2Cu layer, and Al4Cu9 layer was formed at the interface of the T2 copper/1060Al vacuum diffusion joint. The corrosion resistance varied in different regions of the diffusion layer. The corrosion degree in the diffusion layer region on the copper side was relatively mild. In the diffusion layer region on the aluminum side, the pitting holes developed into pitting pits, and with the passage of time, irregular deep gullies were formed, which eventually developed into exfoliation corrosion. In terms of the corrosion resistance, the base materials and each diffusion layer were ranked as follows: T2Cu > Al4Cu9 > AlCu > Al2Cu > 1060Al.

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田继鹏,丁云龙,邵文杰,等. 铜/铝异种金属扩散焊接头耐腐蚀性能研究[J].有色设备,2025,39(4):69-74,99.

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  • 收稿日期:2025-03-31
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  • 在线发布日期: 2025-11-13
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