锌精矿硫酸化焙烧工艺及冶金过程模拟研究
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作者单位:

长沙有色冶金设计研究院有限公司, 湖南 长沙 410011

作者简介:

王翀(1992—),男,陕西渭南人,工程师,硕士,主要从事有色金属冶炼、冶金资源综合利用工艺设计及研究工作。

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中图分类号:

TF812;TF801.2

基金项目:

广西科技重大专项资助项目(桂科AA22067076)


Simulation study on sulfating roasting process and metallurgical process of zinc concentrate
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Changsha Engineering & Research Institute of Nonferrous Metallurgy Co, Ltd.,Changsha 410000 ,China

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    摘要:

    锌精矿资源日益匮乏,成分愈发复杂,加之硫酸化焙烧化学反应过程复杂,利用传统冶金计算方法开展模拟工作量大、效率低。本文介绍了硫化锌精矿硫酸化焙烧工艺、反应机理及酸化焙烧技术特点,利用METSIM对该工艺过程开展了详细模拟计算。着重描述了METSIM模型创建过程原则、步骤,硫酸化焙烧单元模块划分、过程控制。结果表明,15.7万t/a硫化锌精矿硫酸化焙烧可以产出73804.80t/a焙砂,62768.22t/a烟尘,SO2含量为8.8%的烟气48734.22Nm3/h;90.62%的热收入来自于硫化物氧化分解,烟气、烟尘、焙砂、水分蒸发等物料带走了76.63%的热量。计算结果为硫酸化焙烧工艺设计及升级改造,设备大型化、超大型化提供了详实的理论依据。

    Abstract:

    The resources of zinc concentrate are becoming increasingly scarce and the composition is becoming more complex as well as the chemical reaction process of sulfation roasting, using traditional metallurgical calculation methods for simulation is labor-intensive and inefficient. This article introduces the sulfurization roasting process, reaction mechanism and acidification roasting technology characteristics of zinc sulfide concentrate, and carries out detailed simulation calculation of this process using METSIM. The principle, steps, module division and process control of METSIM model creation are emphatically described. The results show that the sulfuric acid roasting of 157000t/a zinc sulfide concentrate can produce 73804.80t/a roasted sand, 62768.22t/a smoke dust, and 48734.22Nm3/h of flue gas with SO2 content of 8.8%. 90.62% of the heat income comes from the oxidation and decomposition of sulfides, with materials such as flue gas, smoke, roasted sand,and water evaporation taking away 76.63% of the heat. This provides a detailed theoretical basis for the design and upgrading of the sulfurization roasting process, and the large-scale and super-large-scale equipment.

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王翀,董鹏,刘自亮,等.锌精矿硫酸化焙烧工艺及其冶金过程模拟研究[J].有色设备,2025,39(3):76-83.

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  • 收稿日期:2024-10-15
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  • 在线发布日期: 2025-11-13
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