稀土改性钢中夹杂物应用及机理研究
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作者单位:

1.内蒙古科技大学稀土产业学院(稀土工程技术学院), 内蒙古 包头 014010 ;2.白云鄂博稀土资源研究与综合利用全国重点实验室, 包头稀土研究院, 内蒙古 包头 014030

作者简介:

杨希明(2001—),男,山东淄博人,硕士,主要研究方向为钢中非金属夹杂物生成热力学、动力学。

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中图分类号:

TQ146;TF845

基金项目:

白云鄂博稀土资源研究与综合利用全国重点实验室开放课题(氧硫及镧铈比对18CrNiMo7-6钢中夹杂物赋存状态及调控机理研究NKDHX2025016)


Application and mechanism research of rare earth modified inclusions in steel
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Affiliation:

1.School of Rare Earth Industry (School of Rare Earth Engineering and Technology), Inner Mongolia University of Science and Technology, Baotou 014010 , China ; 2.State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou 014030 , China

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    摘要:

    夹杂物在钢铁冶炼过程中不可避免,主要包括氧化物、硫化物、氮化物和复合夹杂。这些夹杂物的物理性能与钢基体存在显著差异,会导致钢的显微组织和物理性能不连续,进而影响钢的性能和使用寿命。稀土元素作为改性剂,在改善夹杂物性质方面表现出色,主要通过微合金化作用、夹杂物改性作用和改善钢的凝固组织来优化钢的性能。本文主要探讨了稀土元素(RE)在钢铁冶炼中对夹杂物的改性作用及其对钢性能的影响,系统总结了稀土改性夹杂物的现象、规律、机理及其对钢性能的影响,通过分析不同稀土元素(如Ce、La、Y)对钢中夹杂物和组织的影响,探讨了稀土复合添加以及与热处理工艺配合改性夹杂物的效果,涵盖热力学计算、动力学分析对夹杂物改性机理研究等。热力学计算可预测稀土夹杂物的形成顺序和存在形式,优化反应条件,确定稀土元素的最佳添加量。动力学分析表明,稀土夹杂物在钢液温度和冷却过程中容易碰撞粘合长大,上浮去除,有助于降低钢液中的夹杂物含量。通过稀土元素改性夹杂物,可显著改善钢的性能,提高钢的生产效率,对推动钢铁工业的持续发展具有重要意义。

    Abstract:

    Inclusions are inevitable during the steel smelting process, mainly consisting of oxides, sulfides, nitrides and composite. These inclusions have significant physical property differences from the steel matrix, leading to discontinuities in the microstructure and physical properties of the steel, thereby affecting the performance and service life of the steel. Rare earth elements, as modifiers, have shown excellent performance in improving the properties of inclusions, mainly through microalloying, inclusion modification, and improvement of the steel solidification structure to optimize performances of steel. The paper focuses on the modification effects of rare earth elements (RE) on inclusions during steel smelting and their impact on steel performance, systematically summarizes the phenomena, patterns, mechanisms of rare earth-modified inclusions, and their effects on steel properties, analyzes the effects of different rare earth elements (such as Ce, La, Y) on inclusions and structures in steel, discusses the effects of rare earth complex addition and modification of inclusions in conjunction with heat treatment processes, and covers thermodynamic calculations and kinetic analyses of inclusion modification mechanisms. Thermodynamic calculations can predict the formation order and existence form of rare earth inclusions, optimize reaction conditions, and determine the optimal addition amount of rare earth elements. Kinetic analysis shows that rare earth inclusions are prone to collision, agglomeration, and growth during the molten steel temperature and cooling process, floating and removing, which helps to reduce the content of inclusions in the molten steel. The modification of inclusions by rare earth elements can significantly improve the performance of steel, increase the production efficiency of steel, and is of great significance for promoting the sustainable development of the steel industry.

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引用本文

杨希明,任磊,刘玉宝.稀土改性钢中夹杂物应用及机理研究[J].有色设备,2025,39(3):1-20.

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  • 收稿日期:2025-02-19
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  • 在线发布日期: 2025-11-13
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