钠离子电池正极材料Na3(VOPO4)2F研究进展
CSTR:
作者:
作者单位:

1.攀钢集团研究院有限公司 钒钛资源综合利用国家重点实验室, 四川 攀枝花 617000 ;2.昆明理工大学 冶金与能源工程学院 锂离子电池及材料制备技术国家地方联合工程研究中心, 云南 昆明 650093

作者简介:

杨晓平(1998—),男,云南保山人,硕士研究生,主要研究方向为聚阴离子型钠离子电池正极材料。

通讯作者:

中图分类号:

TG146.4+13

基金项目:

钒钛资源综合利用国家重点实验室开放基金项目(2022P4FZG09A);云南省重大科技专项(202202AG050003)


Research progress on Na3(VOPO4)2F cathode material for sodium-ion batteries
Author:
Affiliation:

1.State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization,Panzhihua Iron & Steel Group Research Institute Co.,Ltd.,Panzhihua 617000 ,China ; 2.National and Local Joint Engineering Research Center for Lithium-ion Batteries and Materials Preparation Technology, Key Laboratory of Advanced Battery Materials of Yunnan Province, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093 , China

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    Na3(VOPO4)2F(NVOPF)凭借其高达130mAh/g的比容量、约3.9V的工作电压以及出色的结构稳定性(体积变化小于2%),已然成为钠离子电池(SIBs)领域极具潜力的正极材料之一。在提升NVOPF储钠性能方面,从与各类导电碳材料的杂化处理,到微观形貌的精心设计,再到阴阳离子的掺杂改性,开展了大量工作。本文聚焦于对NVOPF的合成方法与内在原理等维度进行全面梳理,力求深化对NVOPF研究进程的理解。同时,深入阐释NVOPF独特的微观架构及其与储钠性能之间的内在关联。文中不仅详细介绍了NVOPF正极材料当下的研究状况、取得的阶段性进展以及存在的局限性,还对这一材料未来的发展方向予以展望,期待高性能的NVOPF正极材料能够成功迈向实际应用场景,为能源存储领域带来新的突破与变革。

    Abstract:

    Na3(VOPO4)2F (NVOPF) has emerged as a promising cathode material for sodium-ion batteries (SIBs) due to its high specific capacity of up to 130mAh/g, an operating voltage of approximately 3.9V, and excellent structural stability (less than 2% volume change). Extensive research has been conducted to enhance the sodium-storage performance of NVOPF, including hybridization with various conductive carbon materials, design of micro-morphology, and anions-and cations-doping modifications. This paper focuses on the synthesis methods and the intrinsic principles of NVOPF, aiming to deepen the understanding of the research process surrounding this material. Additionally, we provide an in-depth explanation of the unique microstructure of NVOPF and its intrinsic relationship with sodium-storage performance. The paper not only details the current research status of NVOPF cathode materials, including milestones achieved and existing limitations, but also anticipates future development directions for this material. We hope that high-performance NVOPF cathode materials can be successfully applied in practical scenarios, leading to new breakthroughs and advancements in the field of energy storage.

    参考文献
    相似文献
    引证文献
引用本文

杨晓平,李汶交,段建国,等.钠离子电池正极材料Na3(VOPO4)2F研究进展[J].有色设备,2024,38(6):8-21.

复制
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2024-09-26
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2025-11-15
  • 出版日期:
文章二维码