高铁含锡矿氯化及还原-硫化焙烧试验研究
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红河砷业有限责任公司, 云南 个旧 661000

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刘新阳(1981-),男,陕西凤翔人,材料工程师,硕士,主要从事含砷危废资源化和无害化处理工作,现任红河砷业有限责任公司总经理。

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TF814

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Experimental Research on Chlorination and Reduction Sulfide Roasting of High Iron Iin Ore
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    摘要:

    高铁含锡矿是重要的锡矿资源之一,经磁选后的精矿中含Sn0.93%、Fe61.88%,为实现该类型精矿的高效利用,采用氯化还原焙烧工艺,反应温度1000℃,控制试验配比,当焦粉(无烟煤)、氯化钙、石灰添加量分别为6%、5%、2.7%时,精矿中96.88%的锡呈SnCl 4气体挥发,经水吸附可通过电积回收锡;焙烧渣中Sn含量降至0.029%,其他金属Fe、Zn、Cu含量为63.90%、0.062%、0.12%,可直接作为铁矿石出售。同时研究了碳热还原-硫化焙烧处理该类型矿物的可行性,在反应温度1150℃,分别配入6%的焦粉和4%的黄铁矿反应条件下,可实现原料中95%以上的锡以SnS形式挥发,达到回收锡的目的。

    Abstract:

    High iron tin ore is one of the important tin ore resources. The concentrate after magnetic separation contains 0.93% Sn and 0.93% Fe, In order to realize the efficient utilization of this type of concentrate, the chlorination reduction roasting process was adopted, the reaction temperature is 1000℃, and the experimental ratio is controlled. When the coke powder (anthracite), calcium chloride and lime were 6%, 5% and 2.7% respectively, 96.88% of tin in the concentrate volatilized as SnCl 4 gas, and tin could be recovered by electrowinning after water adsorption; the content of Sn in the roasting slag decreased to 0.029%, and other metals such as Fe, Zn and Cu, the content of are 63.90%, 0.062% and 0.12%, which can be directly sold as iron ore. At the same time, the feasibility of treating this type of minerals by carbothermal reduction sulfurization roasting was studied. Under the reaction conditions of 1150℃ and adding 6% coke powder and 4% pyrite respectively, more than 95% of tin in the raw material can be volatilized in the form of SnS to achieve the purpose of recovering tin.

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刘新阳.高铁含锡矿氯化及还原-硫化焙烧试验研究[J].有色设备,2021,35(4):39-42.

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  • 收稿日期:2021-01-12
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  • 在线发布日期: 2025-11-25
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