钒钛磁铁矿直流炉冶炼试验研究
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中国恩菲工程技术有限公司, 北京 100038

作者简介:

郭亚光(1989—),男,博士,高级工程师,主要从事铁基多金属矿高效冶炼、有色金属冶炼、冶金固废综合利用等方面研究工作。

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TF823;TF55

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Experimental Study on Direct Current Furnace Smelting of Vanadium Titanium Magnetite
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China ENFI Engineering Corporation, Beijing 100038 , China

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    摘要:

    为了探究直流炉处理钒钛磁铁矿过程中渣和铁水成分的变化,在分析原料钒钛磁铁矿性质的基础上, 开展理论计算、小试和直流炉扩大试验。 钒钛磁铁矿中 Fe 主要以 Fe3 O4 存在,V、Ti 主要赋存于钛磁铁矿中,理论计算显示加入石灰可大幅降低还原终渣的熔化温度,提高冶炼温度更有利于降低炉渣黏度;小试结果表明,温度升高有利于提高金属回收率,合适的石灰和还原剂配比对渣铁分离效果影响较大,在温度 1580 ℃ 、C/ O 为 1. 0、石灰配比 3. 3% 条件下,尾渣中 Fe、V 含量可分别降至 1. 20% 、0. 27% ;直流炉扩大试验结果表明,渣中铁含量降至 14. 38% ~ 16. 21% 时,渣中钒含量最高,产出终渣中 Fe、V 含量分别为 1. 89% 、0. 39% , Fe、V 回收率分别为 98. 14% 、85. 7% 。

    Abstract:

    Regarding the changes in slag and liquid iron composition during the direct current furnace treatment of vanadium titanium magnetite, Based on the analysis of raw material properties, theoretical calculations, basic experiments, and DC furnace expansion experiments were conducted to investigate the changes in slag and metal composition during the melting reduction process of vanadium titanium magnetite. Fe mainly exists in Fe3O4 in vanadium titanium magnetite, V and Ti mainly exist in titanium magnetite. Theoretical calculations show that adding lime is beneficial for reduce the melting temperature of the final slag, and increasing temperature is more conducive to reducing the viscosity of the slag. The basic experimental results show that an increase in temperature is beneficial for improving the metal recovery rate. The appropriate ratio of lime and reducing agent has a significant impact on the slag gold separation effect. Under the conditions of temperature 1 580 ℃ , C / O ratio of 1. 0, and lime ratio of 3. 3% , the Fe and V contents in the tailings can be reduced to 1. 20% and 0. 27% ; The results of the expanded test of the DC furnace show that when the iron content in the slag decreases to 14. 38% ~ 16. 21% , the vanadium content is the highest. The Fe and V content in the final slag are 1. 89% and 0. 39% , respectively. The calculated Fe and V recovery rates are 98. 14% and 85. 7% , respectively.

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郭亚光,陈奎元,王云,等. 钒钛磁铁矿直流炉冶炼试验研究[J]. 绿色矿冶,2025,41(5):26 - 33.

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  • 收稿日期:2025-06-11
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  • 在线发布日期: 2025-11-13
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