低铜还原浸出液中铁粉沉铜沉砷工艺探索
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云锡文山锌铟冶炼有限公司, 云南 文山 663700

作者简介:

李云(1992—),男,云南临沧人,本科,中级工程师,主要从事有色金属锌、锡、铟冶炼及固废资源化利用工作。

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TF813;TF803

基金项目:

云南省科技厅重大科技专项计划“多金属冶炼低碳节能及二次资源综合回收利用关键技术研究”(202302AB080014)


Study on the Process of Sinking Copper and Arsenic with Iron Powder in Low Copper Reduction Leaching Solution
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Yunxi Wenshan Zinc & Indium Smelting Co., Ltd, Wenshan 663701 ,China

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    摘要:

    本文以含铜量0.52g/L的低铜还原浸出液为原料,采用铁粉进行沉铜、沉砷试验研究,考察了铁粉加入系数、反应时间、反应温度、铜砷比对沉铜和沉砷效果的影响。结果表明,铁粉加入系数是影响沉铜沉砷效果的主要因素,铜砷比对砷的脱除影响较大,反应时间及反应温度对沉铜沉砷效果影响较小;当铁粉加入系数达到1.8,反应温度维持在70℃以上,反应时间为1h,铜砷比为2.36时,沉铜率和沉砷率分别为82.69%、72.73%,沉铜后液中含铜量为0.09g/L,含砷量为0.06g/L。

    Abstract:

    In this paper, the low copper reduction leaching solution with copper content of 0.52g/L was used as raw material, and iron powder was used to carry out copper and arsenic precipitation experiments. The effects of iron powder coefficient, reaction time, reaction temperature and copper arsenic ratio on copper and arsenic precipitation were investigated. The results show that the addition coefficient of iron powder is the main factor affecting the effect of copper precipitation and arsenic precipitation. The ratio of copper to arsenic has a great influence on the removal of arsenic, and the reaction time and reaction temperature have little effect on the effect of copper precipitation and arsenic precipitation. When the iron powder coefficient reaches 1.8, the reaction temperature is maintained above 70℃, the reaction time is 1h, and the ratio of copper to arsenic is 2.36, the copper deposition rate and arsenic deposition rate are 82.69% and 72.73%, respectively. The copper content in the liquid after copper deposition is 0.09g/L, and the arsenic content is 0.06g/L.

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李云,陶家荣,朱应旭,等.低铜还原浸出液中铁粉沉铜沉砷工艺探索[J].绿色矿冶,2025,41(4):84-88.

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  • 收稿日期:2025-04-24
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  • 在线发布日期: 2025-11-13
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