水剂黄药在铜冶炼闪速炉渣浮选中的研究与应用
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广西金川有色金属有限公司, 广西 防城港 538002

作者简介:

朱立(1997—),男,云南宣威人,本科,中级工程师,主要从事闪速熔炼炉渣资源综合回收利用研究工作。

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TD923

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Research and Application of Aqueous Xanthate in Flotation of Copper Smelting Flash Furnace Slag
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Guangxi Jinchuan Nonferrous Metals Co., Ltd, Fangchenggang 538002 , China

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    摘要:

    闪速熔炼炉渣选矿通常采用固体丁基黄药作为捕收剂回收其中的铜金属,固体丁基黄药在实际生产过程中易潮湿、板结,存在配药劳动强度大、安全风险高、人工配药浓度不稳定、作业环境差、环保压力大等诸多问题。以某铜冶炼企业闪速熔炼炉渣为研究对象,从药方研发、药性对比、药剂有效期、药剂浓度控制等方面开展了水剂黄药的研究与应用。研究结果表明,由70%液体丁基钠黄药+27%液体戊基钠黄药+3%稳定剂复配而成的新型水剂黄药,控制其浓度≤40%,可替代固体黄药,新型水剂黄药有效使用周期≤28d。经工业实践应用证明,水剂黄药兼具硫化铜与氧化铜金属捕收能力,可降低尾矿铜金属损失,经济效益明显。

    Abstract:

    Solid butyl xanthate is usually used as collector to recover copper metal in flash smelting slag beneficiation. Solid butyl xanthate is easy to wet and harden in the actual production process, and there are many problems such as high labor intensity, high safety risk, unstable concentration of artificial dispensing, poor working environment and high pressure of environmental protection. Taking the flash smelting slag of a copper smelting enterprise as the research object, the research and application of aqueous xanthate were carried out from the aspects of prescription research and development, drug property comparison, drug validity period and drug concentration control. The results show that the new aqueous xanthate, which is composed of 70% liquid butyl sodium xanthate + 27% liquid amyl sodium xanthate + 3% stabilizer, can replace the solid xanthate when the concentration is controlled less than or equal to 40%. The effective use period of the new aqueous xanthate is less than or equal to 28 days. It has been proved by industrial practice that the water agent xanthate has both copper sulfide and copper oxide metal collecting ability, which can reduce the loss of copper metal in tailings and has obvious economic benefits.

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朱立,杨继宁,姜观辉,等.水剂黄药在铜冶炼闪速炉渣浮选中的研究与应用[J]. 绿色矿冶,2025,41(3):47-51.

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  • 收稿日期:2024-09-19
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  • 在线发布日期: 2025-11-14
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