富氧侧吹熔池熔炼生产金属化镍阳极工艺研究
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1.金川集团股份有限公司, 甘肃 金昌 737100 ; 2.中国恩菲工程技术有限公司, 北京 100038

作者简介:

顾明杰(1967—),男,山东聊城人,教授级高级工程师,主要从事有色金属镍、钴及贵金属冶炼。

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TF815

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Research on the Process of Producting Metallized Nickel Anode Plate by Oxygen Enriched Side-blown Smelting Technology
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    摘要:

    反射炉熔炼二次镍精矿生产镍阳极板工艺,存在燃料的热利用率低、燃料消耗量大,炉体耐火材料使用寿命短、阳极板脆弱易碎、残极率高,熔炼运行成本高、现场操作环境恶劣等问题。本文通过对富氧侧吹熔池熔炼二次镍精矿生产金属化镍阳极板的工艺研究,得到金属化镍锍产品(Ni+Cu≥76%,Fe<3%,S 16%~20%),最佳工艺参数为:在反应温度为1450~1600℃,富氧浓度65%~75%,连续进料速率为100kg/h条件下,氧料比 10~45Nm3/t,还原剂率为0.5%~1%。随着氧料比增加,镍锍的品位逐渐增加,且铁、硫含量逐渐降低,相应的熔渣含镍逐渐升高。富氧侧吹熔池熔炼生产金属化镍阳极板具备工艺可行性,实现二次镍精矿短流程的“熔化、除铁、降硫”的目的,可产出合格的金属化镍阳极板,明显提高镍阳极板成材率,大幅提高热利用率、提高生产效率和产能,并降低了生产成本。

    Abstract:

    The existing process of smelting secondary nickel concentrate in reverberatory furnace to produce nickel anode plate has some problems, such as low heat utilization rate of fuel, large fuel consumption, short service life of furnace refractory, fragile anode plate, high residual electrode rate, high operation cost, bad operation environment, etc. The process research of producing metallized nickel anode plate by smelting secondary nickel concentrate in oxygen enriched side-blown smelting technology has been completed. The composition of metallized nickel matte is Ni+Cu≥76%, Fe<3%, and S 16%-20%. The optimum process parameters was as followed: the reaction temperature was 1450-1600℃, the oxygen concerntration was 65%-75%, the continuous feed rate was 100kg/h, the ratio of oxygen to feed was 10-45Nm3/t, and the reductant rate was 0.5%-1%. The oxygen enriched side-blown bath smelting technology can produce metallized nickel anode plate, realizes the purpose of “melting, iron removal and sulfur reduction” of secondary nickel concentrate, produces high metallized nickel anode plate, improves the yield of nickel anode plate, greatly improves the heat utilization rate, improves the production efficiency and energy production, and reduces the production cost.

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顾明杰,祁永峰,李智,等.富氧侧吹熔炼短流程生产金属化镍阳极工艺研究[J].绿色矿冶,2023,39(5):9-14.

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  • 收稿日期:2023-07-25
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  • 在线发布日期: 2025-11-19
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