电感耦合等离子体原子发射光谱法同时测定铜冶炼白烟尘中铟和锗元素含量
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1.河南中原黄金冶炼厂有限责任公司, 河南 三门峡 472000 ;2.三门峡职业技术学院, 河南 三门峡 472000

作者简介:

孙轲(1983—),女,本科,高级工程师,主要从事化验分析、X荧光检测工作。

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中图分类号:

TF811;TF09;X758

基金项目:

三门峡市科技计划项目(2020010102)


Simultaneous Detection of Indium and Germanium in White Dust of Copper Smelter by Inductively Coupled Plasma Atomic Emission Spectrometry
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    摘要:

    本文利用电感耦合等离子体原子发射光谱法同时测定白烟尘中铟和锗的含量。采用HCl-HNO3体系进行溶样,严格控制炉温及试剂加入时间,使样品溶解完全且澄清。配制铟锗标准溶液,使用ICP-AES仪器进行铟、锗谱线的选择和干扰校正。该方法操作简单、快速、准确、灵敏度高,具有良好的精密度和准确度,锗和铟检出限分别为0.043μg/mL、0.020μg/mL,相对标准偏差( n =7)为1.0%~2.0%,加标回收率为95.61%~99.15%。该方法能够检测铜冶炼白烟尘中铟和锗含量。

    Abstract:

    In this paper, the content of indium and germanium in white dust was detected by inductively coupled plasma atomic emission spectrometry. The sample was dissolved by HCl-HNO3 system, and the furnace temperature and reagent addition time were strictly controlled to make the sample completely dissolved and clarified. Indium germanium standard solution was prepared, and ICP-AES instrument was used to select indium and germanium spectral lines and correct interference. The method is simple, rapid, accurate, sensitive, and has good precision and accuracy. The detection limits of germanium and indium are 0.043μg/mL and 0.020μg/mL, respectively. The relative standard deviation ( n =7) is 1.0%~2.0%, and the recovery rate is 95.61%~99.15%. It can detect the content of indium and germanium in whitedust of copper smelter.

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孙轲,葛笑寒.电感耦合等离子体原子发射光谱法同时测定铜冶炼白烟尘中铟和锗元素含量[J].绿色矿冶,2023,39(3):59-62.

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  • 收稿日期:2023-02-06
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  • 在线发布日期: 2025-11-18
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