铜冶炼环集烟气和制酸尾气脱硫工艺优化改造与实践
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北方铜业垣曲冶炼厂, 山西 垣曲 043700

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褚继军(1976—),男,化工工程师,北方铜业股份有限公司垣曲冶炼厂副厂长,负责生产经营工作。

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TF811;X758

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Optimization of Desulfurization Process of Collected Fugitive Gas and Sulphuric Acid Production Tail Gas Treatment in Copper Smelting
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    摘要:

    某冶炼厂环集烟气脱硫采用钠碱法工艺,制酸尾气脱硫采用活性焦工艺,脱硫装置存在脱硫后尾气无法满足特别排放限值要求(SO2≤100 mg / m 3 ,NOx≤100 mg / m 3 ,颗粒物臆10 mg / m 3 )的问题。 本文在论述现有装置运行现状基础上提出优化改造方案。 重点论述了离子液脱硫原理、工艺流程、设备选型和系统性能,并针对试生产时出现烟气 SO2 浓度波动大、尾气排放 SO2 浓度不稳定、离子液消耗量过大、离子液中硫代硫酸根浓度过高的问题,提出了相应的处理措施。 经过优化改造,烟气尾排中 SO2 浓度低于 100 mg / m 3 ,大部分时间低于 30 mg / m 3 。 实践证明,此次改造脱硫工艺选择正确,设计参数设定合理,装置运行平稳,脱硫达到理想效果。

    Abstract:

    The collected fugitive gas desulfurization of a smelter adopts the sodium alkali process, and the acid tail gas desulfurization adopts the active coke process. The desulfurization device has the problem that the tail gas after desulfurization cannot meet the special emission limit requirements. This paper put forward the optimization scheme on the basis of discussing the operation status of the existing device (SO2≤100mg/m3, NO x ≤100mg/m3, particle content≤10mg/m3). The principle, process flow, equipment selection and system performance of ionic liquid desulfurization were mainly discussed. In view of the problems of large fluctuation of SO2 concentration in flue gas, unstable SO2 concentration in tail gas emission, excessive consumption of ionic liquid and high concentration of thiosulfate in ionic liquid, the corresponding treatment measures were put forward. After optimization, the SO2 concentration in the tail flue gas was less than 100mg/m3, and most of the time is less than 30mg/m3. Practice has proved that the desulfurization process is selected correctly, the design parameters are set reasonably, the device runs smoothly, and the desulfurization achieves the ideal effect.

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褚继军. 铜冶炼环集烟气和制酸尾气脱硫工艺优化改造与实践[J]. 绿色矿冶,2023,39(3):54 - 58.

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  • 收稿日期:2022-09-20
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  • 在线发布日期: 2025-11-18
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