锌浸出渣富氧侧吹处理技术
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1.中国恩菲工程技术有限公司, 北京 100038 ;2.白银有色集团股份有限公司西北铅锌冶炼厂, 甘肃 白银 730900

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许良(1982—),男,硕士,高级工程师,主要从事火法冶金项目方面的设计及管理工作。

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TF813

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Oxygen-enriched Side Blowing Treatment Technology for Zinc Leaching Residue
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    摘要:

    湿法炼锌的浸出渣成分各不相同,但均含有锌、银等有价金属,同时含铅、镉、砷等重金属,属于危险废物,需要进行无害化处理,同时回收其中的有价金属。目前中国主流的锌浸出渣处理技术有回转窑、烟化炉、顶吹炉等。这些技术已经应用多年,技术成熟可靠,但在节能和环保方面还有较大提升空间。近年来,富氧侧吹技术开始成功应用于锌浸出渣处理,主要包括中国恩菲的侧吹浸没燃烧技术和瓦纽科夫式侧吹技术。本文在综述锌浸出渣处理技术现状基础上,介绍锌浸出渣熔池熔炼机理及"侧吹炉+烟化炉"工艺流程,以实际工程案例介绍瓦纽科夫式侧吹炉和侧吹浸没燃烧炉两种侧吹技术在中国锌冶炼工厂的应用,并从炉体结构、生产操作以及技术指标等方面对这两种侧吹技术进行分析比较。中国恩菲的侧吹浸没燃烧技术处理锌浸出渣具有能耗低、熔炼温度可控、操作简单、自动化程度高、开炉成本低、烟气稳定且氮氧化物含量低等优势,未来将成为中国乃至世界湿法锌冶炼渣的主流处理工艺。

    Abstract:

    The leaching residues of zinc hydrometallurgy are different in composition, but all contain valuable metals such as zinc and silver, as well as heavy metals such as lead, cadmium and arsenic. They are hazardous wastes and need to be harmlessly treated and recovered. At present, the main zinc leaching residue treatment technologies in China include rotary kiln, fuming furnace, top blowing furnace and so on. These technologies have been applied for many years, and the technologies are mature and reliable, but there is still much room for improvement in energy conservation and environmental protection. In recent years, oxygen-enriched side-blowing technology has been successfully applied to the treatment of zinc leaching residue, mainly including the side-blowing submerged combustion technology of China ENFI and the Vanukov side-blowing technology. On the basis of summarizing the current situation of zinc leaching residue treatment technology, this paper introduced the melting mechanism of zinc leaching residue molten pool and the process flow of ' side blowing furnace + fuming furnace ', and introduced the application of two side blowing technologies of Vanukov side-blowing furnace and side-blowing submerged combustion furnace in China 's zinc smelting plant, and analyzed and compared the furnace structure, production operation and technical indicators. The side-blowing submerged combustion technology of China ENFI has the advantages of low energy consumption, controllable smelting temperature, simple operation, high degree of automation, low opening cost, stable flue gas and low nitrogen oxide content. In the future, it will become the mainstream treatment process of zinc smelting slag in China and even in the world.

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许良,杨强,张阁,等.富氧侧吹处理锌浸出渣技术[J].绿色矿冶,2023,39(3):19-25.

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  • 收稿日期:2023-04-10
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  • 在线发布日期: 2025-11-18
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