某钨尾矿性质分析及制备新型复合掺合料试验研究
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1.中铁环境科技工程有限公司, 湖南 长沙 410218 ;2.中国建筑科学研究院有限公司, 北京 100013 ; 3.北京华晟创元环境科技有限公司, 北京 100043

作者简介:

黎胜龙(1976—),男,硕士,研究方向:无机固体废弃物综合利用研究。

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TD982

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Property Analysis of a Tungsten Tailings and Experimental Study on Preparation of New Composite Admixture
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    摘要:

    本文对湖南某钨选矿尾矿的粒度、成分、放射性、腐蚀性和浸出毒性等性质进行分析,结果表明该钨尾矿主要成分为SiO2、CaO和Fe2O3,与水泥水化所需的矿物组成基本一致,放射性、腐蚀性和浸出毒性指标均低于国家标准限定值,说明钨尾矿对环境无害,可探索资源化利用。在此基础上,以该钨尾矿作为主要原材料,通过物理激发和化学激发,采用合理的原料配合比和先进的制备工艺,制备一种新型复合掺合料,并分别采用胶砂法和试饼法对新型复合掺合料进行性能检测分析。检测结果表明,5个试样中,钨尾矿微粉用量适中、助磨外加剂和碱性激发剂用量较大的新型复合掺合料的1#和2#试样28d活性指数≥95%,5个试样安定性均合格。在钨尾矿微粉用量不变的情况下,新型复合掺合料的活性指数的增长与助磨外加剂和碱性激发剂的用量成正比,同时碱性激发活化效应对活性指数的提高发挥一定促进作用。

    Abstract:

    In this paper, the particle size, composition, radioactivity, corrosion and leaching toxicity of a tungsten tailings in Hunan were analyzed. The results show that the main components of the tungsten tailings are SiO2, CaO and Fe2O3, which are basically consistent with the mineral composition required for cement hydration. The radioactive, corrosive and leaching toxicity indexes are lower than the limit values of national standard, indicating that the tungsten tailings are harmless to the environment and can be explored for resource utilization. On this basis, using the tungsten tailings as the main raw material, a new type of composite admixture was prepared by physical excitation and chemical excitation, using reasonable raw material mix ratio and advanced preparation process, and the performance of the new composite admixture was tested and analyzed by mortar method and test cake method respectively. The test results show that the 28d activity index of 1# and 2# samples of the new composite admixture with moderate amount of tungsten tailings micropowder, large amount of grinding aid admixture and alkaline activator is ≥95%, and the stability of five samples is qualified. When the amount of tungsten tailings powder is constant, the increase of activity index of new composite admixture is proportional to the amount of grinding aid admixture and alkaline activator, and the activation effect of alkaline excitation plays a certain role in promoting the increase of activity index.

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黎胜龙,缪兵权,秦海兵,等.某钨尾矿性质分析及制备新型复合掺合料试验研究[J].绿色矿冶,2023,39(3):13-18.

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  • 收稿日期:2022-12-06
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  • 在线发布日期: 2025-11-18
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