三元前驱体材料制备过程中高磁物料回收试验研究
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中冶瑞木新能源科技有限公司, 河北 唐山 063200

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曹嘉轩(1996—),男,本科,助理工程师,主要从事三元前驱体生产技术研发工作。

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TF803.2

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Experimental Study on High Magnetic Material Recovery During the Preparation of Ternary Precursor Materials
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    摘要:

    针对三元高磁物料返溶回收有价金属处理工艺流程长、辅料消耗大等问题,提出了高磁物料低成本净化回收高价金属的工艺,研究了永磁棒搅拌速度、磁场强度对高磁物料浸出液中金属异物颗粒吸附效果的影响,同时研究了聚合硫酸铁、硫酸亚铁等不同添加剂对除铁效果的影响,以及采用锰粉、前驱体事故料作中和剂的除铁效果及对溶液成分的影响。试验结果表明:利用永磁棒吸附高磁物料浸出液中金属异物颗粒具有良好的效果,金属颗粒去除率可达91%,搅拌转速无明显影响,永磁棒磁场强度越大,吸附能力越强;中和水解除铁过程中引入聚合硫酸铁、硫酸亚铁,除铁效果差,且加入聚合硫酸铁后过滤困难,而采用前驱体事故料除铁效果最好,除铁率可达90%以上,且不会引入其他杂质影响溶液质量。

    Abstract:

    In order to solve the problems of long process flow and high consumption of auxiliary materials in the recovery of valuable metals from ternary high magnetic materials, a low cost purification and recovery process for high magnetic materials was proposed. The effect of stirring speed and magnetic field intensity of permanent magnet rods on the adsorption effect of metal foreign particles in the leaching solution of high magnetic materials were studied. The effects of different additives such as polymerized iron sulfate and ferrous sulfate on the iron removal effect were also studied, as well as the use of manganese powder. The effect of removing iron from precursor accident materials as a neutralizer on the introduction of impurities. The experimental results show that the use of permanent magnetic rods to adsorb metal foreign particles in the leaching solution of high magnetic materials has a good effect, with a metal particle removal rate of 91%, and the stirring speed has no significant impact on it; The greater the magnetic field intensity of the permanent magnet rod, the stronger the adsorption capacity. The introduction of polymeric iron sulfate and ferrous sulfate during neutralization and hydrolysis for iron removal has poor iron removal efficiency, and it is difficult to filter after adding polymeric iron sulfate; Adding precursor accident materials has the best iron removal effect, with an iron removal rate of over 90%, and no other impurities will be introduced to affect the solution quality.

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曹嘉轩.三元前驱体材料制备过程中高磁物料回收试验研究[J].绿色矿冶,2023,39(2):60-64.

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  • 收稿日期:2022-10-24
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  • 在线发布日期: 2025-11-17
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