聚丙烯酰胺(PAM)对冶炼烟气净化稀酸杂质沉降的影响
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1.河南中原黄金冶炼厂有限责任公司, 河南 三门峡 472000 ;2.河南省黄金资源综合利用重点实验室, 河南 三门峡 472000 ;3.长庆油田第一采油厂采油工艺研究所, 陕西 延安 716000

作者简介:

赵嵘峥(1993—),男,本科,化工工程师,主要从事冶炼烟气制酸生产技术研究及管理工作。

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TF805.3

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Effect of Polyacrylamide (PAM) on Purifying Dilute Acid from Smelting Flue Gas
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    摘要:

    有色冶炼原料多为金属硫化物,火法冶炼过程中产生大量的二氧化硫烟气,通常冶炼烟气用于制酸。在制酸净化工序中,稀酸捕获大量烟气中的含尘杂质,经高效沉降槽沉降后,上清液返回系统,底流送入压滤机过滤,含有价金属的滤饼返回冶炼系统回收。由于冶炼烟气量和杂质含量波动较大,如要满足所有工况下的除杂效率,需增大沉降槽有效沉降面积或提高颗粒沉降速度,导致成本增加。本文进行了使用絮凝剂PAM提高净化稀酸杂质沉降速度的可行性分析,探究不同PAM加药量对净化稀酸杂质沉降的影响,为沉降槽选型提供参考数据,以期提高沉降效率,减小设备规格。实验结果表明,PAM的添加对冶炼烟气净化稀酸中的颗粒沉降有积极作用,对冶炼烟气净化稀酸的成分无显著影响,不会影响烟气净化效果。

    Abstract:

    The raw materials for nonferrous smelting are mostly metal sulfides, and a large amount of sulfur dioxide flue gas is generated during the pyrometallurgical process. Generally, the smelting flue gas is used for acid production. In the purification process of acid production, dilute acid captures a large amount of dust and impurities in the flue gas, which are settled by an efficient sedimentation tank. The supernatant returns to the system, and the underflow is sent to a filter press for filtration. The filter cake containing valuable metals is returned to the smelting system for recovery. The amount of smelting flue gas and impurity content fluctuate greatly. To meet the impurity removal efficiency under all operating conditions, it is necessary to increase the effective settling area of the settling tank or increase the particle settling speed, which increases the costs. This article conducted a feasibility analysis of using flocculant PAM to improve the sedimentation rate of impurities in purified dilute acid, and explored the impact of different PAM dosage on the sedimentation of impurities in purified dilute acid, so as to provide reference data for the selection of sedimentation tank,improve sedimentation efficiency and reduce equipment specifications. The experimental results show that the addition of PAM has a positive effect on particle deposition in refining dilute acid from smelting flue gas, and has no significant impact on the composition of refining dilute acid from smelting flue gas, and does not affect the flue gas purification effect.

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赵嵘峥,张波,韩战旗,等.聚丙烯酰胺(PAM)对冶炼烟气净化稀酸杂质沉降的影响[J].绿色矿冶,2023,39(2):30-33.

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  • 收稿日期:2022-10-17
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  • 在线发布日期: 2025-11-17
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