电解铝生产温室气体排放探讨及减排方向
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中铝郑州有色金属研究院有限公司, 河南 郑州 450041

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李新华(1970—),男,河南荥阳人,博士,教授级高级工程师,研究方向为温室气体排放核算、碳素材料物理分析、氧化铝生产工艺与技术。

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TF821;X322

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Discussion on Greenhouse Gas Emission of Electrolytic Aluminum Production and Measures of Emission Reduction
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    摘要:

    本文介绍了温室气体排放相关的标准、分类和计算方法,重点介绍电解铝工序的碳排放计算方法,提出电解铝生产的减碳方向。电解工序的碳排放涉及直接排放(范围一)和间接排放(范围二),即净阳极消耗和阳极效应产生的PFCs排放以及外购电力排放。按推荐值计算的净阳极消耗吨铝排放为1.503tCO2e,阳极效应产生的PFCs吨铝排放量为0.252tCO2e。根据实测数据计算的阳极净耗吨铝排放量基本在1.5tCO2e以下,而由实测数据计算的吨铝PFCs排放波动较大,为0.32~2.38tCO2e,均大于0.252tCO2e。电解铝生产消耗的电力是铝生产过程最大的间接排放,由于供电排放因子的不同,其排放量为0~16.2tCO2e/t。规范统一的计算测定方法是得到准确排放量数据的前提。国家相关部门和大型铝业集团应积极组织测定电解铝行业的直接排放,尤其是PFCs排放。降低阳极消耗,减少阳极效应是降低电解铝工序直接排放的关键,节电则是降低间接排放的关键,节约氧化铝等原辅料的消耗是重要手段,采用排放因子低的绿电也是减碳的重要方向。

    Abstract:

    This paper introduced the relevant standards, classification and calculation methods of greenhouse gas emissions, focused on the calculation method of carbon emissions in the electrolytic aluminum process, and put forward the carbon reduction direction of electrolytic aluminum production. The carbon emission of the electrolysis process involves direct emission (scope I) and indirect emission (scope II), namely, the PFCs emission generated by the net anode consumption and anode effect, as well as the emission of purchased power. The net anode consumption per ton of aluminum emission calculated according to the recommended value is 1.503tCO2e, and the PFCs per ton of aluminum emission generated by the anode effect is 0.252tCO2e. The net consumption of aluminum per ton of anode calculated according to the measured data is basically below 1.5tCO2e, while the PFCs emission calculated from the measured data fluctuates greatly from 0.32 to 2.38tCO2e/t, both of which are greater than 0.252tCO2e. The electricity consumed in electrolytic aluminum production is the largest indirect emission in the aluminum production process. Due to different power supply emission factors, its emission is 0~16.2tCO2e/t. Standardized and unified calculation and measurement methods are the prerequisite for obtaining accurate emission data. Relevant national departments and large aluminum industry groups should actively organize the measurement of direct emissions of electrolytic aluminum industry, especially PFCs emissions. Reducing anode consumption and anode effect is the key to reduce the direct emission of electrolytic aluminum process, saving electricity is the key to reduce indirect emission, saving the consumption of raw and auxiliary materials such as aluminum oxide is an important means, and adopting green electricity with low emission factor is also an important direction of carbon reduction.

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李新华.电解铝生产温室气体排放探讨及减排方向[J]. 绿色矿冶,2023,39(2):5-10.

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  • 收稿日期:2022-09-27
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  • 在线发布日期: 2025-11-17
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